Heroes or villains who approximate Character Alignment is "Chaotic Neutral", known as the "Free Spirit" or "Individualist" alignment.
Chaotic Neutral characters are wild, unpredictable and often follow their own personal code without a care for others - they are often selfish and unpleasant and the only thing predictable about them is their unpredictable natures. Even so, they still have a limit they do not cross. Vast majority of heroes that fall under this alignment are Anti-Heroes and often walk a very thin line between good and bad, hence some of them are villains as well.
Their polar opposite is the Lawful Neutral alignment.
Pure Good heroes NEVER fall under this alignment. The type of Pure Good hero that falls under the chaotic character alignment always falls under Chaotic Good. Pure Evil villains NEVER fall under this alignment. The type of Pure Evil villain that falls under the chaotic character alignment always falls under Chaotic Evil.
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Ferra & Torr -
James (Pokemon) -
Woody Woodpecker -
Ursula (The Little Mermaid) -
Lois Griffin -
Stewie Griffin -
Gideon the Cat -
Bo' Rai Cho
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