Like in the previous four seasons, color-coordinated episodes indicate that they focus on specified characters. Episodes are labeled as "Missions", and are all titled in English.
| Mission | Title | Plot |
| 1 | Rivals
(Raibaruzu) |
|
| 2 | Return
(Ritān) |
|
| 3 | Advent
(Adobento) |
|
| 4 | Team Ultra-Z
(Chīmu Urutora Zetto) |
|
| 5 | Hawlucha
(Luchabull) (Rutchaburu) |
|
| 6 | Rouge Collar
(Rūju Karā) |
|
| 7 | Beige Canine
(Beiji Kenain) |
|
| 8 | Border Collie
(Bōdā Korī) |
|
| 9 | White Labrador
(Howaito Raburadōru) |
|
| 10 | Miracle Child
(Mirakuru Tchairudo) |
|
| 11 | Super Saiyan
(Super Saiyajin) (Sūpā Saiyajin) |
|
| 12 | To Simsala
(Tu Shimusara) |
|
| 13 | The Flame Icejin
(Flame Icejin) (Fureimu Aisujin) |
|
| 14 | A New Enemy
(New Enemy) (Nyū Enemī) |
|
| 15 | Monster
(Monsutā) |
|
| 16 | Titan
(Taitan) |
|
| 17 | Clash
(Kurashi) |
|
| 18 | The Strongest of the Strongest
(Strongest of Strongest) (Sutrongesto obu Sutrongesto) |
|
| 19 | Brother
(Burazā) |
|
| 20 | Father
(Fazā) |
|
| 21 | Ancestor
(Ansesutā) |
|
| 22 | Goodbye
(Gūdobai) |
|
| 23 | Fight
(Faito) |
|
| 24 | Unarmed
(Anāmudo) |
|
| 25 | Disband
(Disubando) |
|
| 26 | Hunter
(Hantā) |
|
| 27 | Alter
(Arutā) |
|
| 28 | Cyborg
(Saibgōu) |
|
| 29 | Arus
(Altea) (Aurtea) |
|
| 30 | Voltron
(GoLion) (Goraion) |
|
| 31 | Mistake
(Misuteiku) |
|
| 32 | Regroup
(Rigurūpu) |
|
| 33 | Miracle
(Mirakuru) |
|
| 34 | Duet
(Dyuetto) |
|
| 35 | Continue
(Kontinyū) |
|
| 36 | Resume
(Rizūmu) |
|
| 37 | ||
| 38 | ||
| 39 | ||
| 40 | ||
| 41 | ||
| 42 | ||
| 43 | Azure
(Azyuru) |
|
| 44 | For Reality
(Fō Riaritī) |
|
| 45 | The Final Round
(Final Round) (Fainaru Raundo) |
|
| 46 | The Final Battle
(Final Battle) (Fainaru Batoru) |
|
| 47 | Demise
(Dimaizu) |
|
| 48 | Revival
(Ribaibaru) |
|
| 49 | Gold
(Gorudo) |
|
| FINAL MISSION |
To Eternity
(Tu Itānitī) |